Molar Heat of Vaporization Equation:
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Molar heat of vaporization (ΔH_v) is the amount of energy required to vaporize one mole of a substance at its boiling point under standard pressure. It represents the energy needed to overcome intermolecular forces during the phase change from liquid to gas.
The calculator uses the molar heat of vaporization equation:
Where:
Explanation: The equation calculates the total energy required to vaporize a given amount of substance based on its molar heat of vaporization.
Details: Molar heat of vaporization is a fundamental thermodynamic property used in chemical engineering, thermodynamics, and material science. It helps determine energy requirements for industrial processes like distillation, evaporation, and refrigeration.
Tips: Enter the number of moles and the molar enthalpy of vaporization. Both values must be positive numbers. The result will be in joules (J).
Q1: What is the typical range for molar heat of vaporization values?
A: Molar heat of vaporization values vary widely by substance. Water has a high value of 40.65 kJ/mol, while ethanol is 38.56 kJ/mol, and diethyl ether is 26.52 kJ/mol.
Q2: How does molar heat of vaporization relate to intermolecular forces?
A: Substances with stronger intermolecular forces (like hydrogen bonding) have higher molar heats of vaporization as more energy is required to separate the molecules.
Q3: Does temperature affect molar heat of vaporization?
A: Yes, molar heat of vaporization decreases with increasing temperature and becomes zero at the critical point where liquid and gas phases become indistinguishable.
Q4: How is molar heat of vaporization measured experimentally?
A: It's typically measured using calorimetry techniques where the energy input required to vaporize a known amount of substance is precisely measured.
Q5: What's the difference between molar heat of vaporization and specific heat of vaporization?
A: Molar heat of vaporization is per mole (J/mol), while specific heat of vaporization is per gram (J/g). They're related through the substance's molar mass.